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In your experiment, you are separating casein from milk. Casein is found naturally in cow's milk: however, the amount of casein in a typical glass of milk would only fill a couple of thimbles! To get this sticky stuff away from the rest of the milk, which isn't very sticky, you add vinegar. Vinegar contains an acid, and it causes the casein to precipitate (in other words, it turns the casein into a solid). Now, the casein can be easily separated from the rest of the milk, which is a liquid. The problem now is that casein isn't very sticky after being reacted with acid. Plus, these curds are kind of like cottage cheese - you wouldn't want to stick paper together with this, would you? (yuck!). To make it into a glue, you must add a base. A base is the chemical opposite of an acid. In your experiment, the base is sodium bicarbonate (commonly known as 'baking soda'). When you add it to the curds, it reacts to make the casein soluble again (no longer chunky!), and it is now sticky like a glue.
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